Effect of sulphuric acid on concrete with iron ore tailings

Researches into the uses of waste materials are increasingly being explored to meet up society’s needs and global protection for sustainable, safe and economic development. This paper assessed concrete with iron ore tailings (IOT) exposed to dilute sulphuric acid. Iron ore tailings are the materials left-over after separating the valuable fraction from the uneconomic fraction of an ore. To study the effect of sulphuric acid, concrete of 100 mm cube with a different mix ratios containing IOT were prepared and cured for 28 days in water. The cubes were later immersed into dilute sulphuric acid at a concentration of 5%. The compressive strength of concrete at 7, 28 and 90 days of water curing were determined. Mass loss and strength reduction due to sulphuric effect were evaluated at 7, 28 and 90 days respectively. XRD microstructure of concrete specimens was analysed. Test results indicated that the IOT could be used in concrete as sand replacement since the concrete with IOT has similar trend in compressive strength loss and mass loss to sulphuric acid attack compared to control specimen. The mineralogical crystal failure patterns due to the sulphuric acid in terms X-ray diffraction analysis are the same for control and IOT concrete

Structural differences in amyloid-β fibrils from brains of non-demented elderly individuals and Alzheimer's disease patients

Although amyloid plaques composed of fibrillar amyloid-β (Aβ) assemblies are a diagnostic hallmark of Alzheimer's disease (AD), quantities of amyloid similar to those in AD patients are observed in brain tissue of some nondemented elderly individuals. The relationship between amyloid deposition and neurodegeneration in AD has, therefore, been unclear. Here, we use solid-state NMR to investigate whether molecular structures of Aβ fibrils from brain tissue of nondemented elderly individuals with high amyloid loads differ from structures of Aβ fibrils from AD tissue. Two-dimensional solid-state NMR spectra of isotopically labeled Aβ fibrils, prepared by seeded growth from frontal lobe tissue extracts, are similar in the two cases but with statistically significant differences in intensity distributions of cross-peak signals. Differences in solid-state NMR data are greater for 42-residue amyloid-β (Aβ42) fibrils than for 40-residue amyloid-β (Aβ40) fibrils. These data suggest that similar sets of fibril polymorphs develop in nondemented elderly individuals and AD patients but with different relative populations on average

Nonlinear single-electron tunneling through individually coated colloid particles at room temperature

Single-electron tunneling (SET) has been observed with nanometer coated colloid gold particles at room temperature. We have made the smallest (3-nm) thiol- and silicon dioxide (SiO2)-coated gold particles, from which we obtained SET signals using a scanning tunneling microscope (STM)images reveal individual particles supported by an atomically flat metal surface. The STM tip is used to obtain SET signals from the individual particles, whose shapes have been characterized. The current-voltage curves of the particles exhibit well-defined Coulomb staircases that resemble those obtained at 4.2 K, indicating a strong Coulomb repulsive interaction at room temperature. The clear Coulomb staircases are due to a nonlinearity in the current steps. We suggest a possible mechanism for the nonlinearity in terms of many-body excitations in the particle. We have also identified the region of the particles, where the SET signal originates, using current-imaging-tunneling spectroscopy. We describe the advantages of using the coated nanometer particles for making devices for room-temperature operations

Benchmark notch test for life prediction

Aircraft gas turbine engine components are subjected to severe stress, temperature, and environmental conditions. Economic and reliabilty demands have prompted inordinate effort in development of analytic methods to predict stresses and strains in aircraft engines. There remains, however, the need to check or verify these analytical methodologies against actual experimental data measurements. The laser interferometric strain displacement gage was recognized as having the potential to accomplish this task and was employed in this program. The actual strains incurred at the root of a discontinuity in cyclically loaded test samples subjected to inelastic deformation at high temperature where creep deformation readily occur were measured. The steady-state, cyclic stress-strain response at the root of the discontinuity in the tested samples was analyzed for comparison with the measured results. A comprehensive set of local notch root strain measurements for a variety of load patterns in an Inconel 718 notch specimen at 649 C (1200 F) was obtained and documented using the laser interferometric strain displacement gage

Non-Existence of Time-Periodic Solutions of the Dirac Equation in a Reissner-Nordstrom Black Hole Background

It is shown analytically that the Dirac equation has no normalizable, time-periodic solutions in a Reissner-Nordstrom black hole background; in particular, there are no static solutions of the Dirac equation in such a background field. The physical interpretation is that Dirac particles can either disappear into the black hole or escape to infinity, but they cannot stay on a periodic orbit around the black hole.Comment: 24 pages, 2 figures (published version